File photo. Credit: Canadian Nuclear Laboratories
File photo. Image Credit: Canadian Nuclear Laboratories.

The Canadian Nuclear Laboratories has been awarded a contract to produce new radiation-resisting space-focused materials for the Canadian Space Agency.

The two-year contract for $1 million, with an optional extension to a third year, is part of the Canadian Space Agency’s (CSA) Space Technology Development Program. CNL will be looking into how to create new โ€œnanomaterialsโ€ that durably protect against radiation while being lightweight enough to be feasibly launched into space.ย 

In an interview with SpaceQ, project director Zahra Yamani discussed the project and what theyโ€™re looking to accomplish.

Radiation in Space

She said that managing radiation is a serious concern in space, and is likely to become even more so as the space industry moves into cislunar space and farther. While radiation is an issue on Earthโ€”itโ€™s a growing issue in chip designโ€”itโ€™s far more of a concern in space. 

On Earth, weโ€™re protected from solar particle events (SPEs) and galactic cosmic rays (GCRs) by the Earthโ€™s atmosphere and magnetosphere. The atmosphere blocks harmful particles from entering, while the magnetosphere reflects and redirects potentially dangerous cosmic radiation.

In space, none of those protections apply. Spacecraft in low Earth orbit may benefit slightly from the magnetosphere, but anything beyond it is exposed to the full brunt of cosmic particles and radiation. And while large geosynchronous satellites can be designed to mitigate these effects, it remains a significant concern for crewed cislunar and interplanetary spaceflight. 

On Earth, we also deal with terrestrially-produced radiation through other means, like the water used in nuclear power plants and the lead used by x-ray technicians. Those solutions are either difficult or unfeasible in space due to the weight; getting the necessary volume of lead and/or water into orbit would be prohibitively expensive. “Active” protection that uses magnetic fields, similar to Earthโ€™s magnetosphere, is also not really an option; Yamani said that “the energy you need for replicating the magnetic fields around your spacecraftโ€ฆis not feasible with current technology.”

Space travel requires a different solution. Thatโ€™s what CNL is being paid by the CSA to explore, in the hopes that Canadian research can provide that solution to this pressing issue. Yamani said that the focus is on “advanced multi-functional nanomaterials” intended to tackle SPEs, GCRs, and whatever other radiation threatens the spacecraft and its crew.

Interactions and integrity

Yamani elaborated on how this issue is even more complex than it seems, pointing to two key dilemmas: secondary radiation and material integrity. 

The first problem is surprising, but the radiation that comes from the spacecraft itself can be as damaging as the radiation coming from outside of it. As cosmic radiation hits the spacecraft, it is possibleโ€”even likelyโ€”that materials found in the spacecraft will interact with that radiation. Some will produce radiation of their own. Protections that could work against the radiation coming from space may not work against the types being generated by these materials, and these second-order effects are difficult to predict. Any materials being developed will need to protect against these secondary sources as well.

The other problem is less surprising, but will require a lot of work to resolve. Just as the heat shield on a re-entry vehicle is burned away as it passes through the atmosphere, materials exposed to space radiation can and likely will be affected by it. Any materials the CNL works with will not only need to be tested for their strength, weight, conductivity, flammability, toxicity and other factors, but will also need to be tested again and again as theyโ€™re being exposed to different types of radiation. 

Will the protective materials become weak, brittle, or toxic due to the radiation? Could they become radioactive themselves? Astronauts will need to know, and the CNL needs to sort out those issues before itโ€™s put to use. 

Nanomaterials

This whole process is slated to last two years, with an extra year as a possibility. Yamani admitted that itโ€™s still early days yet, but as stated earlier, she said that their focus is on nanomaterials: materials where at least one dimension can be measured between 1 and 100 nanometers. Nanomaterials are getting a lot of attentionโ€”lattice-shaped carbon nanotubes are being hailed for their strength and excellent conductivityโ€”as a new and potentially fruitful branch of cutting-edge materials science. 

In the case of radiation protection, carbon nanotubes wouldnโ€™t work. Yamani said that a different type may, though. Through previous research with the National Research Council (NRC), theyโ€™ve discovered that Boron-Nitride Nanotubes (BNNTs), which include boron and nitrogen in their lattices, may have the properties theyโ€™re looking for. Their study discovered that while a composite material including BNNTs was degraded by gamma irradiation, the BNNTs themselves โ€œdid not show significant changeโ€, as โ€œthe elastic modulus and the ultimate tensile strength of the nanocomposites did not exhibit significant changeโ€.  

Boron is also, Yamani explained, potentially valuable in protecting against radiation. Cosmic radiation can produce destructive free neutrons which can do damage to a spacecraft and its crew. Boron can absorb slower โ€œthermalโ€ neutronsโ€”she said it has โ€œa very high absorption cross-section for thermal neutrons,โ€ and she said that other lighter elements like hydrogen can neutralize โ€œfastโ€ neutrons. Yamani said that Lithium is also a good candidate for the composite, which was borne out by earlier research in 2019 into Lithium Hydride in shielding. And theyโ€™re looking at other kinds of radiation, like proton radiation and gamma rays.

The CNLโ€™s job will be to discover what composition of elements and materials can be incorporated with the nanotubes to block both cosmic radiation and the particles that it can generate. She said that even heavier materials like lead โ€œcould be interleaved into the fabricโ€ of the lightweight boron nitride nanotubes, providing additional protection while still keeping the composite comparatively lightweight.

In CNLโ€™s press release, Yamani characterized it as โ€œtactical elements and configurations.โ€ When asked, she reiterated that framing of materials-science-as-strategy, and that โ€œthe choice of these tactical elementsโ€ will help dictate their ultimate choice of materials for testing.

A Long Process

Yamani granted that itโ€™s still early days. While theyโ€™ve done the work with NRC on BNNTs, and there is some other research that they can draw on, theyโ€™re still at the beginning of a long process to develop these materials. 

She said that the project will start off with heavy and detailed computer modeling. While computer modeling is not going to capture all the idiosyncrasies of the material before, during, and after its irradiation, it can provide useful guidance on whatโ€™s working and what isnโ€™t. 

Yamani said that CNL has access to โ€œa variety of simulation modelsโ€, including MCNP (Monte-Carlo N-Particle Transport Codes), CERNโ€™s โ€œGEANT4โ€ particle simulation toolkit, and the FLUKA (FLUktuierende KAskade) simulation package. All of these are used to simulate the transport of particles (like radiation) through various materials, including simulating the physics of each of the projectile particlesโ€™ collisions. CNL will use these tools to simulate different materials, iterating on what works, discovering these new โ€œtactical elements and configurationsโ€ until they find appropriate candidates. 

Once thatโ€™s done, she said that “we will get [candidate samples] fabricated at nano-fabrication facilities at NRC.” CNL will carefully test their physical characteristics, then theyโ€™ll begin living up to the โ€œnuclear laboratoryโ€ moniker, exposing the candidates to all manner of different kinds of radiation. Yamani cautioned that no decision has been yet made on which facilities could be used for this, but she mentioned Chalk River Laboratories, the Reactor Materials Testing Laboratory at Queenโ€™s University, and the Royal Military Collegeโ€™s SLOWPOKE-2 research reactor as possibilities.  

Owing to the heavy focus on simulation, Yamani said this irradiation process will likely only start sometime in the second year of the project.

After irradiation, CNL will not only check to see if the material successfully blocked or scattered the radiation, but also repeat all the physical measurements they did earlier. Theyโ€™ll be testing for how and whether the materials were degraded by the irradiation, to determine exactly how long theyโ€™ll last in space. Will they be long-lasting, or will there need to be consistent replacements? Is there a โ€œsweet spotโ€ of cost, weight, protection and durability? Thatโ€™s their issue.

If and when the proper materials are found, Yamani said that they will begin exploring where and how the materials can be used, and reaching out to NRC and its industry partners about mass production. She mentioned shielding for spacecraft as one example, but pointed to the non-conductivity of BNNTs as a possible way to use them in electronics. She also said they could be used in spacesuits, and perhaps even in clothing. 

Nothing is off the table for these nanomaterials and their โ€œtactical elements and configurations.โ€ They could change human spaceflight. For CNL, itโ€™s just a question of finding the right ones.

Craig started writing for SpaceQ in 2017 as their space culture reporter, shifting to Canadian business and startup reporting in 2019. He is a member of the Canadian Association of Journalists, and has a Master's Degree in International Security from the Norman Paterson School of International Affairs. He lives in Toronto.

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